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Effect of electrolyte concentration on the tribological performance of MAO coatings on aluminum alloys

Chao Wang, Jun Chen, Jihua He, Jing Jiang, Qinyong Zhang

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 1065-1071 doi: 10.1007/s11705-019-1909-x

摘要： Micro-arc oxidation (MAO) is an efficient approach to improve the hardness, wear resistance, and other properties of aluminum alloys. In order to investigate the effect of the electrolyte concentration on the properties of MAO coatings for LY12 alloy, the voltage variation during the MAO process was recorded. The surface morphologies and phase compositions of the coatings produced with different electrolytes were investigated using scanning electron microscopy and X-ray diffraction, respectively. The roughness and thickness of the coatings were measured using a pocket roughness meter and an eddy-current thickness meter, respectively. The tribological performances of the coatings were investigated against GCr15 bearing steel on a ball-on-disc wear tester in open air. The results showed that with an increase in the Na SiO content, the working voltage of the MAO process decreased, the roughness and thickness of the coatings increased significantly, and the relative content of the -Al O phase decreased. With an increase in the KOH content, the working voltage decreased slightly, the roughness and thickness of the coatings increased slightly, and the α- and -Al O phase contents remained unchanged. The friction coefficient and wear rate of the coatings increased with an increase in the Na SiO and KOH concentrations. A decrease in the porosity and roughness and an increase in the α-Al O content of the coatings reduced their wear mass loss.

关键词： aluminum alloy     micro-arc oxidation     coating     electrolyte concentration     tribological performance    

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framework-derived whisker-shaped nickel phyllosilicate toward efficiently enhanced mechanical, flammable and tribological

《化学科学与工程前沿（英文）》 2022年 第16卷 第10期   页码 1493-1504 doi: 10.1007/s11705-022-2168-9

摘要： Metal−organic framework-derived materials have attracted significant attention in the applications of functional materials. In this work, the rod-like nickel-based metal−organic frameworks were first synthesized and subsequently employed as the hard templates and nickel sources to prepare the whisker-shaped nickel phyllosilicate using a facile hydrothermal technology. Then, the nickel phyllosilicate whiskers were evaluated to enhance the mechanical, thermal, flammable, and tribological properties of epoxy resin. The results show that adequate nickel phyllosilicate whiskers can disperse well in the matrix, improving the tensile strength and elastic modulus by 13.6% and 56.4%, respectively. Although the addition of nickel phyllosilicate whiskers could not obtain any UL-94 ratings, it enhanced the difficulty in burning the resulted epoxy resin nanocomposites and considerably enhanced thermal stabilities. Additionally, it was demonstrated that such nickel phyllosilicate whiskers preferred to improve the wear resistance instead of the antifriction feature. Moreover, the wear rate of epoxy resin nanocomposites was reduced significantly by 80% for pure epoxy resin by adding 1 phr whiskers. The as-prepared nickel phyllosilicate whiskers proved to be promising reinforcements in preparing of high-performance epoxy resin nanocomposites.

关键词： metal−organic framework     nickel phyllosilicate     whisker     epoxy resin     mechanical response     tribological performance     flammable property    

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Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing

Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1281-1295 doi: 10.1007/s11705-020-2007-9

摘要： Poor interfacial adhesion and dispersity severely obstruct the continued development of carbon nanotube (CNT)-reinforced epoxy (EP) for potential applications. Herein, hierarchical CNT nanohybrids using nickel phyllosilicate (Ni-PS) as surface decorations (CNT@Ni-PS) were synthesized, and the nanocomposites derived from varied mass fractions of EP and CNT@Ni-PS were prepared. The morphological structures, tribological performances, curing behaviors and thermal properties of EP/CNT@Ni-PS nanocomposites were carefully investigated. Results show that hierarchical CNT nanohybrids with homogeneous dispersion and well-bonded interfacial adhesion in the matrix are successfully obtained, presenting significantly improved thermal and tribological properties. Moreover, analysis on cure kinetics proves the excellent promotion of CNT@Ni-PS on the non-isothermal curing process, lowering the curing energy barrier steadily.

关键词： nickel phyllosilicate     surface decoration     tribological property     curing kinetics     thermal performance    

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Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

《化学科学与工程前沿（英文）》 2022年 第16卷 第4期   页码 484-497 doi: 10.1007/s11705-021-2074-6

摘要： The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process. The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method, and the morphology and lamellar structure were examined carefully. Several properties of mechanical, thermal and tribological responses of epoxy nanocomposites were performed. It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix, and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected. In addition, friction coefficient and wear rate were increased first and then decreased along with the particle content, and showed the lowest values at a mass fraction of 5%. Nevertheless, the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin (EP) nanocomposites. This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites.

关键词： nickel phyllosilicate     flow-like structure     mechanical property     thermal stability     tribological performance    

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Facile synthesis of polyaniline nanorods to simultaneously enhance the mechanical properties and wear resistance of epoxy composites

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1254-1266 doi: 10.1007/s11705-023-2297-3

摘要： To enhance the mechanical properties and wear resistance of epoxy resin, polyaniline nanorods were first synthesized using a facile route, and then introduced into the epoxy matrix to yield composites via solution mixing. Several measurements were conducted to investigate the phase structures and compositions of polyaniline nanorods, and their positive influences on the mechanical and tribological properties of epoxy resin were also characterized. The results confirmed that the as-synthesized polyaniline exhibited representative rod-like morphologies and dispersed well in the epoxy matrix, leading to significant enhancements in the tensile strength and elastic modulus of epoxy composites. The highest values of 110.33 MPa and 2.04 GPa were obtained by adding 5%–7% polyaniline nanorods, which were 43% and 62% higher than the pure sample, respectively. The wear rate was increased first and then decreased along with polyaniline nanorods, presenting the lowest value of 2.12 × 10−5 mm3·Nm–1 by adding 5% filler, which was markedly reduced by ca. 70% compared to the control sample. Finally, the possible wear mechanism was proposed and discussed in detail. This study tried to broaden the applications of polyaniline nanorods in the field of tribology.

关键词： epoxy resin     polyaniline nanorods     mechanical property     tribological performance     wear mechanism    

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Erratum to: Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological

《化学科学与工程前沿（英文）》 2022年 第16卷 第10期   页码 1530-1530 doi: 10.1007/s11705-022-2240-5

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Tribological mechanism of carbon group nanofluids on grinding interface under minimum quantity lubrication

《机械工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0733-z

摘要： Carbon group nanofluids can further improve the friction-reducing and anti-wear properties of minimum quantity lubrication (MQL). However, the formation mechanism of lubrication films generated by carbon group nanofluids on MQL grinding interfaces is not fully revealed due to lack of sufficient evidence. Here, molecular dynamic simulations for the abrasive grain/workpiece interface were conducted under nanofluid MQL, MQL, and dry grinding conditions. Three kinds of carbon group nanoparticles, i.e., nanodiamond (ND), carbon nanotube (CNT), and graphene nanosheet (GN), were taken as representative specimens. The [BMIM]BF4 ionic liquid was used as base fluid. The materials used as workpiece and abrasive grain were the single-crystal Ni–Fe–Cr series of Ni-based alloy and single-crystal cubic boron nitride (CBN), respectively. Tangential grinding force was used to evaluate the lubrication performance under the grinding conditions. The abrasive grain/workpiece contact states under the different grinding conditions were compared to reveal the formation mechanism of the lubrication film. Investigations showed the formation of a boundary lubrication film on the abrasive grain/workpiece interface under the MQL condition, with the ionic liquid molecules absorbing in the groove-like fractures on the grain wear’s flat face. The boundary lubrication film underwent a friction-reducing effect by reducing the abrasive grain/workpiece contact area. Under the nanofluid MQL condition, the carbon group nanoparticles further enhanced the tribological performance of the MQL technique that had benefited from their corresponding tribological behaviors on the abrasive grain/workpiece interface. The behaviors involved the rolling effect of ND, the rolling and sliding effects of CNT, and the interlayer shear effect of GN. Compared with the findings under the MQL condition, the tangential grinding forces could be further reduced by 8.5%, 12.0%, and 14.1% under the diamond, CNT, and graphene nanofluid MQL conditions, respectively.

关键词： grinding     minimum quantity lubrication     carbon group nanofluid     tribological mechanism    

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Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

《机械工程前沿（英文）》 2012年 第7卷 第1期   页码 93-98 doi: 10.1007/s11465-012-0313-8

摘要：

Hydrogen peroxide (H2O2) is a kind of ideal green propellant. It is crucial to study the wear behavior and failure modes of the metal materials under the strong oxidizing environment of H2O2. This study aims to investigate the wear of rubbing pairs of 2Cr13 stainless steel against 1045 metal in H2O2 solutions, which has a great effect on wear, the decomposition and damage mechanism of materials. The comparison analysis of the friction coefficients, wear mass loss, worn surface topographies and current densities was conducted under different concentrations of H2O2 solutions. There were significant differences in the tribological and electrochemistry properties of the rubbing pairs in different H2O2 solutions.

关键词： hydrogen peroxide     wear     corrosion     wear mechanism    

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Tribological study on the surface modification of metal-on-polymer bioimplants

《机械工程前沿（英文）》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0682-6

摘要： The tribological performance of artificial joints is regarded as the main factor of the lifespan of implanted prostheses. The relationship between surface roughness and coefficient of friction (COF) under dry and lubricated conditions is studied. Results show that under dry test, friction coefficient is not reduced all the time with a decrease in surface roughness. On the contrary, a threshold of roughness value is observed, and frictional force increases again below this value. This critical value lies between 40 and 100 nm in Sa (roughness). This phenomenon is due to the transfer of friction mechanisms from abrasion to adhesion. Under wet test, COF always decreases with reduction in surface roughness. This result is mainly attributed to the existence of a thin layer of lubricant film that prevents the intimate contact of two articulating surfaces, thus greatly alleviating adhesion friction. Furthermore, surface texturing technology is successful in improving the corresponding tribological performance by decreasing friction force and mitigating surface deterioration. The even-distribution mode of texturing patterns is most suitable for artificial joints. By obtaining the optimal surface roughness and applying texturing technology, the tribological performance of polymer-based bioimplants can be greatly enhanced.

关键词： artificial joints     surface roughness     friction     surface texturing    

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Application of Cu nanoparticles as N32 base oil additives

Qiang HE, Jun YE, Hongzhao LIU, Jinling LI,

《机械工程前沿（英文）》 2010年 第5卷 第1期   页码 93-97 doi: 10.1007/s11465-009-0083-0

摘要： Cu nanoparticles as N32 base oil additives are studied in the paper and their structure is characterized by transmission electron microscopy (TEM) and X-ray powder diffraction spectroscopy (XRD). The widely used steel-steel friction system is chosen to test the feasibility and practicality of Cu nanoparticles as bearing lubricant additives. The results show that N32 base oil with 0.5% Cu nanoparticle can improve the test sample contact fatigue life than pure N32 base oil.

关键词： Cu nanoparticle     tribological property     contact fatigue     weibull distribution    

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Tribological properties of onion like fullerenes and NiFe

Ruixiang WANG,Yihao ZHANG,Haizhou WU

《能源前沿（英文）》 2021年 第15卷 第1期   页码 208-212 doi: 10.1007/s11708-017-0454-x

摘要： A novel way for a compressor to improve its coefficient of performance and enhance its reliability by employing nano-refrigeration lubricant oil was proposed. Onion like fullerenes (OLFs) and NiFe O nano-composites, modified by Span 80, were dispersed in refrigeration oil KFR22 by solid grinding (SG). Morphologies of NiFe O nano-composites were characterized by using transmission electron microscope (TEM). The tribological properties as a refrigeration lubricants additive were investigated using SRV (II), a multi-functional reciprocating friction and wear tester. The results showed that the friction coefficient was decreased from 0.15 to 0.04.

关键词： refrigeration lubricants     friction coefficient     nano-composites     reciprocating motion     onion like fullerenes    

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Performance-based and performance-driven architectural design and optimization

Xing SHI

《结构与土木工程前沿（英文）》 2010年 第4卷 第4期   页码 512-518 doi: 10.1007/s11709-010-0090-6

摘要： As the architecture, engineering, and construction (AEC) industry is marching into the sustainable and low-carbon era, the performance of architecture has drawn more attention than ever. Simulation technology has made quantified analysis of architectural performance possible and, therefore, directly enables architects and engineers to incorporate performance analysis into the design work flow. It is argued that performance-based and performance-driven architectural designs differ in that the latter involves computer-aided optimization technique so that the performance can be used as the criteria to truly “drive” the design. The paper starts with a brief introduction of performance issues in architectural design, followed by a review of the evolution of performance-based architectural design. The concept of performance-driven architectural design is presented, and some design projects and research work are reviewed. The driving engine, i.e., optimization technique, and its application in architectural design is discussed. Challenges to making performance-driven design a common practice are explained, and a schematic of integrated performance-based/driven architectural design software is proposed.

关键词： performance     optimization     architectural design     simulation     sustainability    

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Flexural and longitudinal shear performance of precast lightweight steel–ultra-high performance concrete

《结构与土木工程前沿（英文）》 2023年 第17卷 第5期   页码 704-721 doi: 10.1007/s11709-023-0941-6

摘要： In this study, the flexural and longitudinal shear performances of two types of precast lightweight steel–ultra-high performance concrete (UHPC) composite beams are investigated, where a cluster UHPC slab (CUS) and a normal UHPC slab (NUS) are connected to a steel beam using headed studs through discontinuous shear pockets and full-length shear pockets, respectively. Results show that the longitudinal shear force of the CUS is greater than that of the NUS, whereas the interfacial slip of the former is smaller. Owing to its better integrity, the CUS exhibits greater flexural stiffness and a higher ultimate bearing capacity than the NUS. To further optimize the design parameters of the CUS, a parametric study is conducted to investigate their effects on the flexural and longitudinal shear performances. The square shear pocket is shown to be more applicable for the CUS, as the optimal spacing between two shear pockets is 650 mm. Moreover, a design method for transverse reinforcement is proposed; the transverse reinforcement is used to withstand the splitting force caused by studs in the shear pocket and prevent the UHPC slab from cracking. According to calculation results, the transverse reinforcement can be canceled when the compressive strength of UHPC is 150 MPa and the volume fraction of steel fiber exceeds 2.0%.

关键词： precast steel–UHPC composite beam     flexural performance     longitudinal shear performance     parametric study     transverse reinforcement ratio    

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Experimental research on cyclone performance at high temperature

LI Wenqi, CHEN Jianyi

《机械工程前沿（英文）》 2007年 第2卷 第3期   页码 310-317 doi: 10.1007/s11465-007-0055-1

摘要： To predict the influence of operating temperatures on cyclone performance, an experimental investigation was conducted on particle separation in a reverse flow, tangential volute-inlet cyclone separator with a diameter of 300 mm and with air heated up to 973 K. The test powder silica has a mass median diameter of 10 um, while inlet velocity range was 12-36 m/s. Both the separation efficiency and pressure drop of the cyclone were measured as a function of the inlet velocity and operating temperature. At the same inlet velocity, both the separation efficiency and pressure drop decrease with increasing temperature. In addition, optimum inlet velocity, at which the cyclone has its highest separation efficiency, tends to increase with a rise in temperature. An analysis on our own data and published results has shown that the fractional efficiency of a cyclone is a definite function of dimensionless numbers such as the Stokes number, the Reynolds number, the Froude number, dimensionless cyclone inlet area, and dimensionless outlet diameter. A nondimensional experimental correlation of the cyclone performance, including the influence of temperature, was obtained on the basis of our own previous work. The prediction of the influence of temperature on separation efficiencies and pressure drops is in fairly good agreement with experimental results.

关键词： diameter     definite function     nondimensional experimental     cyclone performance     influence    

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Comparison of indices for stiffness performance evaluation

Giuseppe CARBONE, Marco CECCARELLI,

《机械工程前沿（英文）》 2010年 第5卷 第3期   页码 270-278 doi: 10.1007/s11465-010-0023-z

摘要： This paper addresses the problem of a numerical evaluation of the stiffness performance for multibody robotic systems. An overview is presented with basic formulation concerning indices that are proposed in literature. New indices are also outlined. Stiffness indices are computed and compared for a case study. Results are used for comparing the effectiveness of the stiffness indices. The main goal is to propose a performance index describing synthetically the elastostatic response of a multibody robotic system and also for design purposes.

关键词： robotics     stiffness     performance indices    

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标题 作者 时间 类型 操作

Effect of electrolyte concentration on the tribological performance of MAO coatings on aluminum alloys

Chao Wang, Jun Chen, Jihua He, Jing Jiang, Qinyong Zhang

期刊论文

framework-derived whisker-shaped nickel phyllosilicate toward efficiently enhanced mechanical, flammable and tribological

期刊论文

Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing

Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li

期刊论文

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

期刊论文

Facile synthesis of polyaniline nanorods to simultaneously enhance the mechanical properties and wear resistance of epoxy composites

期刊论文

Erratum to: Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological

期刊论文

Tribological mechanism of carbon group nanofluids on grinding interface under minimum quantity lubrication

期刊论文

Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

期刊论文

Tribological study on the surface modification of metal-on-polymer bioimplants

期刊论文

Application of Cu nanoparticles as N32 base oil additives

Qiang HE, Jun YE, Hongzhao LIU, Jinling LI,

期刊论文

Tribological properties of onion like fullerenes and NiFe

Ruixiang WANG,Yihao ZHANG,Haizhou WU

期刊论文

Performance-based and performance-driven architectural design and optimization

Xing SHI

期刊论文

Flexural and longitudinal shear performance of precast lightweight steel–ultra-high performance concrete

期刊论文

Experimental research on cyclone performance at high temperature

LI Wenqi, CHEN Jianyi

期刊论文

Comparison of indices for stiffness performance evaluation

Giuseppe CARBONE, Marco CECCARELLI,

期刊论文